Rate constants of the reaction between alkyl radicals and oxygen and stable nitroxyl radicals

  • A. L. Aleksandrov
  • E. M. Pliss
  • V. F. Shuvalov
Physical Chemistry


The rate constants of the reaction between the alkyl radicals of hydrocarbons (R.) and of vinyl monomers (M.) and O2 and stable nitroxyl radicals
were determined at 50‡C. The low-molecular-weight radicals react with O2 (k1) and the
(k3) more rapidly than the M. do. For polar R. and M. k1 and k3 are close, and for the nonpolar ones k1>k3.


Oxygen Hydrocarbon Vinyl Alkyl Radical Nitroxyl 
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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • A. L. Aleksandrov
    • 1
    • 2
  • E. M. Pliss
    • 1
    • 2
  • V. F. Shuvalov
    • 1
    • 2
  1. 1.Branch of the Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka
  2. 2.Yaroslav Polytechnic InstituteUSSR

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