Reaction of polynitroalkane salts with halogen derivatives of antimony

  • V. I. Erashko
  • S. A. Shevelev
Organic Chemistry
  • 21 Downloads

Conclusions

In the reaction of trinitromethane and 1,1-dinitromethane salts with Ph2SbCl,α-polynitroalkylstibines are formed, irrespective of the nature of the cation (Ag+ or K+), i.e., the reaction proceeds at theα-C atom of polynitrocarbanion. In reactions with Ph4SbBr, tetraphenylstibonium salts of polynitroalkanes are formed.

Keywords

Antimony Halogen Halogen Derivative Trinitromethane Tetraphenylstibonium 

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • V. I. Erashko
    • 1
  • S. A. Shevelev
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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