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Reaction of phosphonyl radicals with sterically hindered carbonyl compounds

  • R. N. Nasirov
  • B. L. Tumanskii
  • N. A. Malysheva
  • N. N. Godovikov
  • N. N. Bubnov
  • A. I. Prokof'ev
  • S. P. Solodovnikov
  • M. I. Kabachnik
Organic Chemistry
  • 28 Downloads

Conclusions

  1. 1.

    Phosphonyl radicals add to di-tert-butyl-p-benzoquinone either at the carbonyl O atom to form a phenoxyl radical, or at the multiple bond of the ring to form a cyclopentadienyl radical. The reaction of phosphonyl radicals with sterically hindered methylenequinones proceeds in a similar way.

     
  2. 2.

    Phosphonyl radicals add to 4,4-dialkyl-2,6-di-tert-butyl-2,5-cyclohexadien-1-ones at the ring multiple bond only to form the corresponding cyclopentadienyl radicals.

     
  3. 3.

    Phosphonyl radicals add to 3,3,5,5-tetra-tert-butyldiphenoquinone at the multiple bond of the ring at the 1(1) and 2(2) positions, and to the O atom to form the corresponding radicals.

     

Keywords

Carbonyl Carbonyl Compound Multiple Bond Phenoxyl Phenoxyl Radical 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • R. N. Nasirov
    • 1
  • B. L. Tumanskii
    • 1
  • N. A. Malysheva
    • 1
  • N. N. Godovikov
    • 1
  • N. N. Bubnov
    • 1
  • A. I. Prokof'ev
    • 1
  • S. P. Solodovnikov
    • 1
  • M. I. Kabachnik
    • 1
  1. 1.N. A. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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