Effect of the medium on the phosphorylation of monoethanolamine
- 21 Downloads
The rate constants and product ratios of N- and O-phosphorylation of monoethanolamine by p-nitrophenyl phenyl chloromethylphosphonate in different solvents were determined.
In dipolar aprotic solvents phosphorylation of both reaction centers of monoethanolamine occurred to a commensurate degree, while in weakly polar solvents phosphorylation at oxygen predominated.
KeywordsOxygen Phenyl Reaction Center Polar Solvent Aprotic Solvent
Unable to display preview. Download preview PDF.
- 1.R. Greenhalgh and M. A. Weinberger, Can. J. Chem.,45, 495 (1967).Google Scholar
- 2.R. Greenhalgh, R. M. Heggie, and M. A. Weinberger, Can. J. Chem.,48, 1351 (1970).Google Scholar
- 3.P. M. Zavlin and V. M. Shek, Zh. Obshch. Khim.,42, 1257 (1972).Google Scholar
- 4.V. E. Bel'skii, L. S. Novikova, L. A. Kudryavtseva, and B. E. Ivanov, Zh. Obshch. Khim.,48, 1512 (1978).Google Scholar