Synthesis of formylcyclopentadienyltricarbonylrhenium and some of its properties

  • N. E. Kolobova
  • Z. P. Valueva
  • M. Ya. Solodova
Organic Chemistry

Conclusions

  1. 1.

    Formylcyclopentadienyltricarbonylrhenium, cyanocyclopentadienyltricarbonylrhenium, and cyanocyclopentadienyltricarbonylmanganese were synthesized.

     
  2. 2.

    Formylcyclopentadienyltricarbonylrhenium is reduced by LiAlH4, to hydroxymethylcyclopentadienyltricarbonylrhenium. The condensation of formylcyclopentadienyltri.carbonylrhenium with 2,4-dinitrophenylhydrazine, aniline, and the acetyl derivatives of cyclopentadienyltricarbonylmanganese, cyclopentadienyltricarbonylrhenium, and -ferroceneleads to the formation of the corresponding 2,4-dinitrophenylhydrazones, Schiff bases, and α,β-unsaturated ketones.

     

Keywords

Ketone Acetyl Aniline Schiff Base Schiff 

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • N. E. Kolobova
    • 1
  • Z. P. Valueva
    • 1
  • M. Ya. Solodova
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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