Dehydrogenation of n-decane on deposited techetium catalysts
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We were the first to study the catalytic properties of technetium deposited on Al2O3 in the dehydrogenation of n-decane and it was shown that alumina-technetium catalysts have a relatively high activity and selectivity in the formation of monoolefins.
It was established that among the elements of the manganese subgroup in their activity in the dehydrogenation of n-decane the metals, deposited on Al2O3, fall into the order: Tc > Re ≫ Mn.
KeywordsAl2O3 Manganese High Activity Dehydrogenation Catalytic Property
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- 1.H. Kubicka, J. Catal.,12, 223 (1969).Google Scholar
- 2.V. I. Spitsyn, O. N. Pirogova, and N. M. Prokhorets, in: Heterogeneous Catalysis. Data of Third All-Union Conference on Mechanism of Catalytic Reactions [in Russian], Novosibirsk, Izd. Sib. Otd. Akad. Nauk SSSR (1982), p. 126.Google Scholar
- 3.V. I. Spitsyn, N. M. Prokhorets, and G. N. Pirogova, Dokl. Akad. Nauk SSSR,261, 432 (1981).Google Scholar
- 4.U.S. Patent 3,868,333 (1975); Chem. Abstr.,83, 45675d (1975).Google Scholar
- 5.G. V. Isagulyants, O. D. Sterligov, A. P. Barkova, and T. V. Babashova, Dokl. Akad. Nauk SSSR,270, No. 4 (1983).Google Scholar
- 6.A. A. Klyachko-Gurvich, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1884 (1961).Google Scholar
- 7.G. V. Isagulyants, O. D. Sterligov, A. P. Barkova, L. K. Maslova, and E. F. Shubochkina, Izv. Akad. Nauk SSSR, Ser. Khim., 434 (1982).Google Scholar