1,1-Bis(trifluoromethyl)hydrazine

  • É. G. Bykhovskaya
  • A. F. Gontar'
  • I. L. Knunyants
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Conclusions

  1. 1.

    The stable 1,1-bis(trifluoromethyl)hydrazine was synthesized by the thermal decomposition of either tert-butyl bis(trifluoromethyl)carbamate or a solution of bis(trifluoromethyl) carbamic acid azide in the presence of water, and its reaction with perfluoro-2-aza-propene, bis(trifluoromethyl)ketene, and hexafluoroacetone was studied.

     
  2. 2.

    The dhydration of the adduct of 1,1-bis(trifluoromethyl)hydrazine with hexafluoroacetone by oleum gave hexafluoroacetone bis(trifluoromethyl)hydrazone, the first member of the perfluorohydrazones.

     

Keywords

Adduct Thermal Decomposition Azide Hydrazine Carbamate 

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Literature cited

  1. 1.
    A. F. Gontar, É. G. Bykhovskaya, A. S. Vinogradov, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2632 (1981).Google Scholar

Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • É. G. Bykhovskaya
    • 1
  • A. F. Gontar'
    • 1
  • I. L. Knunyants
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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