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Some transformations of 9-m-carboranylthiol

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Samples of 9-o- and 9-m-carboranylsulfenyl chlorides, aryl (9-m-carboranyl) sulfides, phenyl(9-m-carboranyl)sulfoxide, and phenyl(9-m-carboranyl) sulfone were prepared for the first time.

  2. 2.

    Similar to alkylsulfinic acids, 9-m-carboranylsulfinic acid readily disproportionates to give 9-m-carboranylthiolsulfonate and 9-m-carboranylsulfonic acid.

  3. 3.

    9-m-Carboranylthiol adds to compounds with an activated double bond in the presence of base.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. I. Zakharkin & I. V. Pisareva

Authors
  1. L. I. Zakharkin
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  2. I. V. Pisareva
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 396–402, February, 1984.

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Zakharkin, L.I., Pisareva, I.V. Some transformations of 9-m-carboranylthiol. Russ Chem Bull 33, 355–361 (1984). https://doi.org/10.1007/BF00951070

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  • DOI: https://doi.org/10.1007/BF00951070

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