Hydrolysis and chemiluminescence of diazaquinones. Communication 3. Investigation of mechanism of chemiluminescence

  • B. A. Rusin
  • A. N. Leksin
Physical Chemistry
  • 20 Downloads

Conclusions

  1. 1.

    Possible mechanisms have been examined critically in the chemiluminescence generated by hydrolysis of diazaquinones in the presence of O2. The chemiluminescence has two kinetic stages, “fast” and “slow.” Attention has been concentrated mainly on the “slow” chemiluminescence, which is related to the principal channel of diazaquinone consumption in terms of mass consumed.

     
  2. 2.

    It has been shown that slow chemiluminescence is generated with the participation of phthalhydrazides formed in the process of diazaquinone hydrolysis. It is suggested that the slow chemiluminescence appears as a result of the interaction of acyl radicals with the phthalhydrazide.

     

Keywords

Hydrolysis Acyl Radical Kinetic Stage Phthalhydrazide Principal Channel 

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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • B. A. Rusin
    • 1
  • A. N. Leksin
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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