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Mixed anhydrides of α-mercuriohexafluoroisobutyric acids

  • I. L. Knunyants
  • E. M. Rokhlin
  • A. Yu. Volkonskii
Organic Chemistry

Conclusions

  1. 1.

    Mercury salts of carboxylic acids are readily added on to bis(trifluoromethyl) ketene and its N-phenylimine, forming mixed anhydrides or imides of α-mercuriobishexafluoroisobutyric acid.

     
  2. 2.

    The mixed anhydride of trifluoroacetic and α-mercuriobishexafluoroisobutyric acids is readily decomposed to bis(trifluoromethyl) ketene, trifluoroacetic anhydride, and the internal salt of α-mercuriohexafluoroisobutyric acid. On decarboxylation in pyridine this salt is converted to hexafluoroisopropylidenemercury.

     

Keywords

Mercury Pyridine Anhydride Carboxylic Acid Ketene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    E. M. Rokhlin, A. Yu. Volkonskii, and E. I. Mysov, Izv. Akad. Nauk SSSR, Ser. Khim., 1359 (1978).Google Scholar
  2. 2.
    B. L. Dyatkin, N. I. Delyagina, and S. R. Sterlin, Usp. Khim.,45, 1218 (1976).Google Scholar
  3. 3.
    B. L. Dyatkin, L. G. Zhuravkova, B. I. Martynov, E. I. Mysov, S. R. Sterlin, and I. L. Knunyants, J. Organomet. Chem.,31, C15 (1971).Google Scholar
  4. 4.
    V. R. Polishchuk, L. S. German, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 620 (1971).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • I. L. Knunyants
    • 1
  • E. M. Rokhlin
    • 1
  • A. Yu. Volkonskii
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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