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The reaction of 1,1,1-trichloro-2,2-bis(p-chlorophehyl)ethane with vinylidene chloride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane with vinylidene chloride leads to the intermediate formation of the radicals Ar2CHCCl2CH2CCl2, which undergo cyclization with subsequent dehydrochlorination, 2,4,6-trichloro-1-(p-chlorophenyl)naphthalene being formed. The reaction is of preparative value for the synthesis of polychlorinated naphthalenes.

  2. 2.

    A method has been developed for the analysis of mixtures containing low-volatility polychloro-aromatic compounds by high-performance liquid chromatography.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. A. Kuz'mina, A. A. Karapetyan, E. Ts. Chukovskaya & R. Kh. Freidlina

Authors
  1. N. A. Kuz'mina
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  2. A. A. Karapetyan
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  3. E. Ts. Chukovskaya
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  4. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1814–1817, August, 1979.

We thank V. I. Dostovalova for participating in the discussions of the PMR spectra obtained.

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Kuz'mina, N.A., Karapetyan, A.A., Chukovskaya, E.T. et al. The reaction of 1,1,1-trichloro-2,2-bis(p-chlorophehyl)ethane with vinylidene chloride. Russ Chem Bull 28, 1675–1678 (1979). https://doi.org/10.1007/BF00950992

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  • DOI: https://doi.org/10.1007/BF00950992

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