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The reaction of 1,1,1-trichloro-2,2-bis(p-chlorophehyl)ethane with vinylidene chloride

  • N. A. Kuz'mina
  • A. A. Karapetyan
  • E. Ts. Chukovskaya
  • R. Kh. Freidlina
Organic Chemistry

Conclusions

  1. 1.

    The reaction of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane with vinylidene chloride leads to the intermediate formation of the radicals Ar2CHCCl2CH2CCl2, which undergo cyclization with subsequent dehydrochlorination, 2,4,6-trichloro-1-(p-chlorophenyl)naphthalene being formed. The reaction is of preparative value for the synthesis of polychlorinated naphthalenes.

     
  2. 2.

    A method has been developed for the analysis of mixtures containing low-volatility polychloro-aromatic compounds by high-performance liquid chromatography.

     

Keywords

Chloride Chromatography Liquid Chromatography Ethane Naphthalene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    R. Kh. Freidlina, M. A. Rozhkova, N. A. Kuz'mina, and E. Ts. Chukovskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 374 (1975).Google Scholar
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    P. A. Bristow, P. N. Brittain, C. M. Riley, and B. F. Williamson, J. Chromatography,131, 57 (1977).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • N. A. Kuz'mina
    • 1
  • A. A. Karapetyan
    • 1
  • E. Ts. Chukovskaya
    • 1
  • R. Kh. Freidlina
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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