Conclusions
When α-hydrohexafluorothiolisobutyric acid is reacted with bis (trifluoromethyl) ketene, the initial act is addition bo the C=O multiple bond of the latter.
Literature cited
Y. A. Cheburkov and I. L. Knunyants, Fluor. Chem. Rev.,1, 107 (1967).
L. A. Simonyan, Z. V. Safronova, N. P. Gambaryan, M. Yu. Antipin, and Yu. T. Struchkov, Izv. Akad. Nauk SSSR, Ser. Khim.,1980, 358.
M. G. Voronkov, N. A. Keiko, T. A. Kuznetsova, V. A. Pestunovich, and I. D. Kalikhman, Dokl. Akad. Nauk SSSR,247, 110 (1979).
E. G. Ter-Gabriélyan, É. P. Lur'e, Yu. V. Zeifman, and N. P. Gambaryan, Izv. Akad. Nauk SSSR, Ser. Khim., 1380 (1975).
M. S. Raasch, J. Org. Chem.,37, 1347 (1972).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2408–2410, October, 1982.
Rights and permissions
About this article
Cite this article
Bekker, R.A., Rozov, L.A., Popkova, V.Y. et al. Addition of nucleophilic reagents to bis(trifluoromethyl) ketene. Russ Chem Bull 31, 2123–2125 (1982). https://doi.org/10.1007/BF00950674
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00950674