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Gas chromatographic separation of some stereoisomeric dioxolanes and their identification using PMR spectroscopy

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We accomplished the preparative separation of a number of stereoisomeric 1,3-dioxolanes by the circulatory GLC method with an efficiency greater than 30 thousand theoretical plates.

  2. 2.

    Using the PMR spectra of 2-substituted 4,5-diisopropyl-1,3-dioxolanes, we identified the isomers on the basis of differences in the chemical shifts of the signals from the proton and substituent in the 2 position in cis-syn and cis-anti isomers.

  3. 3.

    We determined the thermodynamic parameters of solution for the indicated stereoisomers. The given compounds have very small differences in the thermodynamic characteristics.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. P. Zabokritskii, V. A. Bukin & B. A. Rudenko

  2. Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Odessa

    M. P. Zabokritskii, V. A. Bukin & B. A. Rudenko

Authors
  1. M. P. Zabokritskii
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  2. V. A. Bukin
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  3. B. A. Rudenko
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2277–2281, October, 1982.

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Zabokritskii, M.P., Bukin, V.A. & Rudenko, B.A. Gas chromatographic separation of some stereoisomeric dioxolanes and their identification using PMR spectroscopy. Russ Chem Bull 31, 2005–2008 (1982). https://doi.org/10.1007/BF00950642

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  • DOI: https://doi.org/10.1007/BF00950642

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