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Effect of the type of carrier on the properties of cobalt catalysts in the synthesis of aliphatic hydrocarbons from carbon monoxide and hydrogen

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Co catalysts that are active in the synthesis of hydrocarbons from CO and H2 are those on which the adsorption of H2 exceeds 3·10−2 mmole/g Co and the adsorption of carbon monoxide exceeds 7·10−2 mmole/g Co.

  2. 2.

    Carbon monoxide and hydrogen are adsorbed on active catalysts in weakly bound forms.

  3. 3.

    A mechanism is proposed for the formation of an active center and the adsorption of carbon monoxide on Co-catalysts which includes the appearance of a partial positive charge on the cobalt atom.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. L. Lapidus, Hoang Chong Jem & A. Yu. Krylova

Authors
  1. A. L. Lapidus
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  2. Hoang Chong Jem
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  3. A. Yu. Krylova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2216–2220, October, 1982.

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Lapidus, A.L., Jem, H.C. & Krylova, A.Y. Effect of the type of carrier on the properties of cobalt catalysts in the synthesis of aliphatic hydrocarbons from carbon monoxide and hydrogen. Russ Chem Bull 31, 1953–1956 (1982). https://doi.org/10.1007/BF00950629

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  • DOI: https://doi.org/10.1007/BF00950629

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