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Reaction of α,α,ω-trichloroalkenes with 1,1,1-trichloroethane and 1,1,1,3-tetrachloropropane, accompanied by rearrangement of radicals

  • N. V. Kruglova
  • R. Kh. Freidlina
Organic Chemistry
  • 18 Downloads

Conclusions

In the reaction of CCl3CH3 with CCl2=CHCH2CH2CH2Cl, and of CCl3CH2CH2Cl with CCl2= CHCH2Cl, initiated by Fe(CO)5+DMF, the main addition products are respectively compounds of structure HCCl2CH(CCl2CH3)CH2CH2CHCl2 and HCCl2CH(CCl2CH2CHCl2)CH2C1. The formation of these compounds was explained by the isomeriza'tion of the radical-adducts CCl2CH(CCl2CH3)CH2CH2CH2Cl and CCl2CH(CCl2CH2CH2Cl)CH2Cl, with migration of a hydrogen atom from the CH2Cl groups found in the 5 position to the radical center.

Keywords

Hydrogen Migration Hydrogen Atom Radical Center Addition Product 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • N. V. Kruglova
    • 1
  • R. Kh. Freidlina
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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