Spectra and structure of sulfonium C-dinitro ylides

  • K. I. Rezchikova
  • O. P. Shitov
  • V. A. Tartakovskii
  • V. A. Shlyapochnikov
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Conclusions

Based on the data of the vibrational spectra of sulfonium C-dinitro ylides and the quantum-chemical calculation of the electronic structure of the\((CH{_3} ){_2} \mathop S\limits^ + - \overline C (NO{_2} ){_2} \) molecule the nitro groups of dinitro ylides in their electronic structure differ substantially from the nitro groups of both the gem-dinitroalkanes and their salts.

Keywords

Sulfonium Nitro Group Vibrational Spectrum Dinitro 

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • K. I. Rezchikova
    • 1
  • O. P. Shitov
    • 1
  • V. A. Tartakovskii
    • 1
  • V. A. Shlyapochnikov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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