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Synthesis and structure of Pd(II) with aniline Pd(NH2C6H5)2·2DMF

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When potassium chloropalladoate is reacted with anilium chloranilate, in aqueous DMF, the chloranilic acid anion does not react.

  2. 2.

    As the reaction product we isolated a crystalline complex of composition PdCl2(NH2C6H5)2·2HCON-(CH3)2, whose structure was studied by the x-ray structure analysis method.

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Literature cited

  1. Z. G. Aliev, S. I. Kondrat'ev, L. O. Atovmyan, M. L. Khidekel', and V. V. Karpov, Izv. Akad. Nauk SSSR, Ser. Khim., 487 (1981).

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Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 6, pp. 1398–1400, June, 1981.

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Aliev, Z.G., Kondrat'ev, S.I., Atovmyan, L.O. et al. Synthesis and structure of Pd(II) with aniline Pd(NH2C6H5)2·2DMF. Russ Chem Bull 30, 1121–1123 (1981). https://doi.org/10.1007/BF00950311

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  • DOI: https://doi.org/10.1007/BF00950311

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