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Cleavage of di- and trioxacyclohexanes by trimethyliodosilane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction of Me3SiI with 1,4-dioxane gives 1,2-diiodoethane, 1,2-bis(trimethylsiloxy)ethane, and hexamethyldisiloxane, while reaction with 1,3,5-trioxane and 2,4,6-trimethyl-1,3-5-trioxane respectively gives theα,α′-diiodomethyl and ethyl ethers and HMDS.

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Literature cited

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    M. G. Voronkov', V. G. Komarov, A. I. Albanov, I. M. Korotaeva & É. I. Dubinskaya

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  1. M. G. Voronkov'
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  2. V. G. Komarov
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  3. A. I. Albanov
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  4. I. M. Korotaeva
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  5. É. I. Dubinskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1391–1392, June, 1981.

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Voronkov', M.G., Komarov, V.G., Albanov, A.I. et al. Cleavage of di- and trioxacyclohexanes by trimethyliodosilane. Russ Chem Bull 30, 1115–1116 (1981). https://doi.org/10.1007/BF00950308

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  • DOI: https://doi.org/10.1007/BF00950308

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