Advertisement

Electrophilic cyclization of (E, E)-2-farnesylthiophene

  • A. V. Semenovskii
  • M. M. Emel'yanov
Organic Chemistry
  • 18 Downloads

Conclusions

The electrophilic cyclization of (E, E)-2-farnesylthiophene has been studied for the first time, and it has been shown that the allylic thienyl group acts as a specific terminator which leads to the formation of a tetra cyclic molecule with a cis-hydrindane fragment.

Keywords

Thienyl Cyclic Molecule Electrophilic Cyclization Thienyl Group 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    A. V. Semenovskii and M. M. Emel'yanov, Izv. Akad. Nauk SSSR, Ser. Khim., 2578 (1980).Google Scholar
  2. 2.
    A. V. Semenovskii, Dissertation, Moscow (1972).Google Scholar
  3. 3.
    C. H. Brieskorn, A. Fuchs, J. B. Bredenberg, J. D. McChesney, and E. Wenkert, J. Org. Chem.,29, 2293 (1964).Google Scholar
  4. 4.
    T. Matsumoto and S. Osui, Chem. Lett., 105 (1978).Google Scholar
  5. 5.
    Ya. L. Gol'dfarb, E. P. Zakharov, A. S. Shashkov, and F. M. Stoyanovich, Zh. Org. Khim.,7, 1253 (1980).Google Scholar
  6. 6.
    W. G. Blenderman, M. M. Joullie, and G. Preti, Tetrahedron Lett., 4985 (1979).Google Scholar
  7. 7.
    A. V. Semenovskii, V. A. Smit, and V. F. Kucherov, Dokl. Akad. Nauk SSSR,168, 606 (1966).Google Scholar
  8. 8.
    Ya. L. Gol'dfarb, C. Z. Taits, and L. I. Belen'kii, Zh. Obshch. Khim.,29, 3564 (1959).Google Scholar
  9. 9.
    R. F. Zürcher, Helv. Chim. Acta,46, 2054 (1963).Google Scholar
  10. 10.
    K. Mori, M. Ohki, A. Sato, and H. Matsui, Tetrahedron,28, 3739 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • A. V. Semenovskii
    • 1
  • M. M. Emel'yanov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

Personalised recommendations