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ESR study of the interaction of mononuclear and binuclear metal carbonyls with silicon hydrides and the use of these systems to generate α-chlorine-containing radicals

  • R. G. Gasanov
  • R. Kh. Freidlina
Physical Chemistry

Summary

  1. 1.

    As a result of the interaction of mononuclear metal carbonyls M(CO)n (M=Cr, Fe, Mo, W) and binuclear metal carbonyls M2(CO)10 (M=Mn, Re) with (C2H5)3SiH and C2H5SiCl2H, the radicals (C2H5)3Si, (C2H5)329Si, (C2H5)SiCl2, and (C2H5)29SiCl2 are formed; these radicals have been detected and identified by ESR, using 2,4,6-tri-tert-butylnitrosobenzene as a spin trap.

     
  2. 2.

    The reaction of a system consisting of a metal carbonyl and (C2H5)3SiH with gempolychlorinated compounds effectively generates α-chlorine-containing radicals.

     

Keywords

Silicon Carbonyl Hydride Spin Trap Metal Carbonyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • R. G. Gasanov
    • 1
  • R. Kh. Freidlina
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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