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Mechanism of interaction of methyltitanium trichloride with 2,2,6,6-tetramethylpiperidine-1-oxyl

  • N. E. Khrushch
  • O. M. Chukanova
  • F. S. D'yachkovskii
  • V. A. Golubev
Physical Chemistry

Summary

  1. 1.
    The interaction of CH3TiCl3 with 2,2,6,6-tetramethylpiperidine-1-oxyl forms the complex
    .
     
  2. 2.
    Decomposition of
    forms CH3 radicals that enter into reactions of recombination with complexes
    within the complex; some of the CH3 radicals escape into the bulk solution.
     
  3. 3.

    The rate constant for the reaction CD3TiCl3+ĊD3 is 2·103 liters/mole.sec at 20°C.

     

Keywords

Recombination Bulk Solution Trichloride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • N. E. Khrushch
    • 1
  • O. M. Chukanova
    • 1
  • F. S. D'yachkovskii
    • 1
  • V. A. Golubev
    • 1
  1. 1.Branch of the Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka

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