Skip to main content
SpringerLink
Log in

Mechanism of the phototransfer of electrons from zinc porphyrins to carbon tetrachloride in glassy matrices

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A one-quantum tunneling mechanism is responsible for the photoionization of Zn porphyrins in glassy matrices containing added acceptors.

  2. 2.

    The relative orientation of the reacting molecules is an important factor in chargeseparation processes in zinc porphyrin-acceptor systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. K. M. Smith (editor), Porphyrins and Metalloporphyrins, Elsevier Sci. Publishing Co., New York (1975).

    Google Scholar 

  2. B. D. Berezin, Coordination Compounds of the Porphyrins and Phthalocyanines [in Russian], Nauka, Moscow (1978).

    Google Scholar 

  3. A. N. Sidorov, Molecular Photonics [in Russian], Nauka, Leningrad (1970), p. 199.

    Google Scholar 

  4. J. Fajer, D. C. Borg, A. F. Orman, D. Dolphin, and R. H. Felton, J. Am. Chem. Soc.,92, 3451 (1970).

    PubMed  Google Scholar 

  5. B. N. Shelimov, V. G. Vinogradova, V. I. Mal'tsev, and N. V. Fok, Dokl. Akad. Nauk SSSR,172, 655 (1967).

    Google Scholar 

  6. B. Ke, S. Demeter, R. F. Khairutdinov, and K. I. Zamaraev, Biochim. Biophys. Acta,265, 545 (1979).

    Google Scholar 

  7. R. F. Khairutdinov, N. A. Sadovskii, V. N. Parmon, M. G. Kuz'min, and K. I. Zamaraev, Dokl. Akad. Nauk SSSR,220, 888 (1975).

    Google Scholar 

  8. R. S. Becker and J. B. Allison, J. Phys. Chem.,67, 2669 (1963).

    Google Scholar 

  9. E. Kh. Brikenshtein, L. N. Strekova, A. N. Asanov, and R. F. Khairutdinov, Khim. Vys. Energ.,15, No. 6 (1981).

  10. K. I. Zamaraev and R. F. Khairutdinov, Usp. Khim.,47, 922 (1978).

    Google Scholar 

  11. C. G. Delbecq, Y. Toyazava, and P. H. Yuster, Phys. Rev.,B9, 4497 (1974).

    Google Scholar 

  12. B. Brocklehurst, J. Phys. Chem.,83, 536 (1979).

    Google Scholar 

  13. I. V. Alexandrov, R. F. Khairutdinov, and K. I. Zamaraev, Chem. Phys.,32, 123 (1978).

    Google Scholar 

  14. A. V. Doctorov, R. F. Khairutdinov, and K. I. Zamaraev, Chem. Phys.,56, 322 (1981).

    Google Scholar 

  15. J. P. Collman, R. R. Gagne, C. A. Reed, T. R. Halbert, G. Lang, and W. T. Robinson, J. Am. Chem. Soc.,97, 1427 (1975).

    PubMed  Google Scholar 

  16. D. Mauzerall, Ann. N. Y. Acad. Sci.,206, 483 (1973).

    PubMed  Google Scholar 

  17. P. Carapellucci and D. Mauzerall, Ann. N. Y. Acad. Sci.,244, 214 (1975).

    PubMed  Google Scholar 

  18. J. P. Collman, J. I. Brauman, K. M. Doxsee, T. R. Halbert, E. Bunnenberg, R. E. Linder, G. N. LaMar, J. D. Gaudio, G. Lang, and K. Spartalian, J. Am. Chem. Soc.,102, 4182 (1980).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    L. N. Strekova, E. Kh. Brikenshtein, A. N. Asanov, N. A. Sadovskii & R. F. Khairutdinov

Authors
  1. L. N. Strekova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Kh. Brikenshtein
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. N. Asanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. A. Sadovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. F. Khairutdinov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1227–1233, June, 1981.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Strekova, L.N., Brikenshtein, E.K., Asanov, A.N. et al. Mechanism of the phototransfer of electrons from zinc porphyrins to carbon tetrachloride in glassy matrices. Russ Chem Bull 30, 965–971 (1981). https://doi.org/10.1007/BF00950273

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00950273

Keywords

Search

Navigation