Conclusions
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1.
Using pulsed radiolysis the authors have investigated the products of one-electron reduction of P2W18O 6−62 and P2W17O 10−61 ions in neutral aqueous solutions. They have determined their optical characteristics and the rate constants of formation.
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2.
The reaction of hydrogen atoms with P2W18O 6−62 in acid aqueous solutions leads to formation of [P2W18O62·H]6−.
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3.
They have established that ionizing radiation stimulates hydrolysis of heteropoly compounds; a mechanism of the process has been proposed.
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A. K. Pikaev, S. A. Kabakchi, I. E. Makarov, and B. G. Ershov, Pulsed Radiolysis and Its Use [in Russian], Atomizdat, Moscow (1980).
A. K. Pikaev, G. K. Sibirskaya, V. M. Shirshov, P. Ya. Glazunov, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,200, 383 (1971).
G. M. Varda, E. Paraconstantinou, and M. T. Pope, Inorg. Chem.,9, No. 3, 662 (1970).
E. Paraconstantinou and M. T. Pope, Inorg. Chem.,9, No. 3, 667 (1970).
E. Paraconstantinou, Z. Phys. Chem.,106, No. 3–6, 283 (1977).
M. V. Mokhosoev, Chemistry of Mo(VI) and W(VI) Compounds [in Russian], Novosibirsk (1979).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1212–1216, June, 1981.
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Ershov, B.G., Sukhov, N.L., Kartashev, N.I. et al. Pulsed radiolysis of aqueous solutions of salts of phophotungstic acids of the 18th and 17th series. Russ Chem Bull 30, 952–956 (1981). https://doi.org/10.1007/BF00950269
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DOI: https://doi.org/10.1007/BF00950269