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Intermolecular hydrogen bonding in β-hydroxycarbonyl ferrocene compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    IR and PMR spectroscopy was used to study the different types of hydrogen bonds formed in solutions of β-hydrocarbonyl ferrocene compounds. The observed spectral behavior can be explained by the formation on an intramolecular hydrogen bond of the OH group with the iron atom only in the case of a dilute solution of the ethyl ester of 3-hydroy-2-(phenylferrocenylmethyl)-3-methylbutanoic acid.

  2. 2.

    Only OH⋯OH− and OH⋯O=C interactions were found for this isomer in the crystalline state.

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Literature cited

  1. Yu. N. Polivin, V. N. Postnov, V. A. Sazonova, D. V. Sagorevskii (Sagorevsky), Yu. S. Nekrasov, and A. P. Kharchevnikov, J. Organomet. Chem.,282, 147 (1985).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. D. Ashkinadze, Yu. N. Polivin, A. I. Yanovskii, Yu. T. Struchkov, V. N. Postnov & V. A. Sazonova

  2. M. V. Lomonosov Moscow State University, USSR

    L. D. Ashkinadze, Yu. N. Polivin, A. I. Yanovskii, Yu. T. Struchkov, V. N. Postnov & V. A. Sazonova

Authors
  1. L. D. Ashkinadze
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  2. Yu. N. Polivin
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  3. A. I. Yanovskii
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  4. Yu. T. Struchkov
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  5. V. N. Postnov
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  6. V. A. Sazonova
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Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1672–1674, July, 1985.

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Ashkinadze, L.D., Polivin, Y.N., Yanovskii, A.I. et al. Intermolecular hydrogen bonding in β-hydroxycarbonyl ferrocene compounds. Russ Chem Bull 34, 1530–1532 (1985). https://doi.org/10.1007/BF00950166

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  • DOI: https://doi.org/10.1007/BF00950166

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