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Reaction of chlorine fluorosulfate with 1-trifluoromethoxy-1,2-dichlorotrifluoroethane and 1,2-dichlorohexafluoropropane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reactivity of chlorine fluorosulfate increases with increasing acidity of the medium. In HSO3F/SbF5, chlorine fluorosulfate under mild conditions replaces the terminal chlorine atom in 1,2-dichlorohexafluoropropane and both chlorine atoms in 1-trifluoromethoxy-1,2-dichlorotrifluoroethane by fluorosulfate groups.

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Literature cited

  1. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, and L. D. Kuznetsova, Izv. Akad. Nauk SSSR, Ser. Khim., 1892 (1974).

  2. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, Nguen Tkhe Ngem and D. V. Zagorevskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1572 (1984).

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  4. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, T. M. Potarina, and L. D. Kuznetsova, Izv. Akad. Nauk SSSR, Ser. Khim., 2641 (1980).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, A. S. Tatarinov & K. I. Pasevina

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  1. A. V. Fokin
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  2. Yu. N. Studnev
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  3. A. I. Rapkin
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  4. A. S. Tatarinov
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  5. K. I. Pasevina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1669–1672, July, 1985.

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Fokin, A.V., Studnev, Y.N., Rapkin, A.I. et al. Reaction of chlorine fluorosulfate with 1-trifluoromethoxy-1,2-dichlorotrifluoroethane and 1,2-dichlorohexafluoropropane. Russ Chem Bull 34, 1527–1530 (1985). https://doi.org/10.1007/BF00950165

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  • DOI: https://doi.org/10.1007/BF00950165

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