Conclusions
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1.
The interaction of ω-haloalkylbenzenechromium tricarbonyl with the metal carbonyl anions [Fe(CO)2C5H5]− and [Re(CO)5]− has been studied and it was shown that the anion [Fe(CO2)· C5H5]− readily formed binuclear complexes.
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2.
Partial dehalogenation occurred on interacting alkyl iodides with [Re(CO)5]− together with the formation of the appropriate σ complexes. Halogen containing chromium tricarbonyl derivatives reacted with [Re(CO)5]− variously depending on the nature of the halogen while under mild conditions one did not react and the other gave exclusively a dehalogenation product.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1644–1647, July, 1985.
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Kaganovich, V.S., Rybinskaya, M.I. Reactions of ω-haloalkylbenzenechromium tricarbonyl with metal-containing nucleophiles. Russ Chem Bull 34, 1503–1506 (1985). https://doi.org/10.1007/BF00950157
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DOI: https://doi.org/10.1007/BF00950157