Skip to main content
SpringerLink
Log in

Reactions of chlorine and bromine fluorosulfates with perfluoroalkyl halides in a strongly acidic medium

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Chlorine fluorosulfate is more active than bromine fluorosulfate in the substitution reaction of halogen atom in alkyl halides by the fluorosulfate group.

  2. 2.

    In a fluorosulfonic acid medium containing antimony pentafluoride, the reaction with chlorine fluorosulfate leads to the substitution of the primary chlorine atom in perfluoro-alkyl chlorides, and also the primary and secondary bromine atoms in perfluoroalkyl bromides by the fluorosulfate group under mild conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, L. D. Kuznetsova, O. V. Verenikin, and I. N. Krotovich, Izv. Akad. Nauk SSSR, Ser. Khim., 2422 (1976).

  2. C. J. Schack and K. O. Christe, J. Fluor. Chem.,16, 63 (1980).

    Google Scholar 

  3. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, and A. S. Tatarinov, Izv., Akad. Nauk SSSR, Ser. Khim., 1916 (1984).

  4. A. V. Fokin, Yu. N. Studnev, L. I. Ragulin, and I. N. Krotlovich, Izv. Akad. Nauk SSSR, Ser. Khim., 1906 (1982).

  5. A. V. Fokin, Yu. N. Studnev, I. N. Krotlovich, G. G. Furin, and G. G. Yakobson, Izv. Akad. Nauk SSSR, Ser. Khim., 927 (1981).

  6. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, and L. D. Kuznetsova, Izv. Akad. Nauk SSSR, Ser. Khim., 1892 (1974).

  7. A. V. Fokin, Yu. N. Studnev, I. N. Krotovich, L. D. Kuznetsova, and O. V. Verenikin, Izv. Akad. Nauk SSSR, Ser. Khim., 806 (1979).

  8. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, T. M. Potarina, and L. D. Kuznetsova, Izv. Akad. Nauk SSSR, Ser. Khim., 2641 (1980).

  9. A. V. Fokin, Yu. N. Studnev, L. D. Kuznetsova, and I. N. Krotovich, Usp. Khim.,51, 1258 (1982).

    Google Scholar 

  10. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, and A. S. Tatarinov, Izv. Akad. Nauk SSSR, Ser. Khim., 1876 (1983).

  11. A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, V. G. Chilikin, and O. V. Verenikin, Izv. Akad. Nauk SSSR, Ser. Khim., 659 (1985).

  12. A. V. Fokin, Yu. N. Studnev, L. D. Kuznetsova, and V. L. Rud', Izv. Akad. Nauk SSSR, Ser. Khim., 471 (1974).

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, A. S. Tatarinov & Yu. V. Seryanov

Authors
  1. A. V. Fokin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. N. Studnev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Rapkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Tatarinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. V. Seryanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1635–1638, July, 1985.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fokin, A.V., Studnev, Y.N., Rapkin, A.I. et al. Reactions of chlorine and bromine fluorosulfates with perfluoroalkyl halides in a strongly acidic medium. Russ Chem Bull 34, 1495–1498 (1985). https://doi.org/10.1007/BF00950154

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00950154

Keywords

Search

Navigation