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X-ray diffraction structural analysis of 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose and 1,6-anhydro-2-dexosy-2,4-di-C-methyl-3,4-di-O-benzyl-β-D-glucopyranose

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The product of the isomerization of 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-4-O-mesyl-β-D-galactopyranose corresponds in structure to 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose. The geometrical and conformational parameters of this compound were determined.

  2. 2.

    The conformation of 1,4-anhydro-2-dexosy-2,4-di-C-methyl-3,4-di-O-benzyl-β-D-glucopyranose was established.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    L. G. Vorontsova, M. O. Dekaprilevich & O. S. Chizhov

Authors
  1. L. G. Vorontsova
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  2. M. O. Dekaprilevich
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  3. O. S. Chizhov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1568–1573, July, 1985.

The authors thank A. F. Sviridov, M. S. Ermolenko, and D. V. Yashunskii for providing the initiative and affording constant interest in this work and for donating high-quality crystals.

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Vorontsova, L.G., Dekaprilevich, M.O. & Chizhov, O.S. X-ray diffraction structural analysis of 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose and 1,6-anhydro-2-dexosy-2,4-di-C-methyl-3,4-di-O-benzyl-β-D-glucopyranose. Russ Chem Bull 34, 1434–1439 (1985). https://doi.org/10.1007/BF00950145

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  • DOI: https://doi.org/10.1007/BF00950145

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