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Molecular and crystal structure of ribitol 1-0-[bis(N-diethylamido)thiophosphate]-2,4; 3,5-bis-O-(N-diethylamidothionephosphate), C21H47N4O5P3S3

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

X-ray diffraction structural analysis indicated that one of the products of the consecutive reaction of ribitol with PCl3, diethylamine, and sulfur is ribitol 1-O-[bis(N-diethylamido)thionephosphate]-2,4;3,5-bis-O-(N-diethylaminothionephosphate). The six-membered heterocycles in this product are in chair conformations and form a condensed 2,4,7,9-tetraoxa-3,8-diophospha-trans-bicyclo[4.4.0]decane system with equatorial orientation of the substituents.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    I. A. Litvinov, Yu. T. Struchkov, B. A. Arbuzov, N. A. Makarova & É. T. Mukmenev

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    I. A. Litvinov, Yu. T. Struchkov, B. A. Arbuzov, N. A. Makarova & É. T. Mukmenev

Authors
  1. I. A. Litvinov
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  2. Yu. T. Struchkov
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  3. B. A. Arbuzov
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  4. N. A. Makarova
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  5. É. T. Mukmenev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1550–1557, July, 1985.

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Litvinov, I.A., Struchkov, Y.T., Arbuzov, B.A. et al. Molecular and crystal structure of ribitol 1-0-[bis(N-diethylamido)thiophosphate]-2,4; 3,5-bis-O-(N-diethylamidothionephosphate), C21H47N4O5P3S3 . Russ Chem Bull 34, 1418–1425 (1985). https://doi.org/10.1007/BF00950142

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  • DOI: https://doi.org/10.1007/BF00950142

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