Mass spectrometry of π complexes of transition metals. Communication 33. Carboranyl derivatives of benzenechromium tricarbonyl

  • N. I. Vasyukova
  • Yu. S. Nekrasov
  • Yu. N. Sukharev
  • G. K. -I. Magomedov
  • A. S. Frenkel'
Physical Chemistry
  • 22 Downloads

Conclusions

  1. 1.

    The degree of fragmentation of carboranyl derivatives of benzenechromium tricarbonyl with cleavage of metal-ligand bonds depends linearly on the number of vibrational degrees of freedom of the π ligand.

     
  2. 2.

    Coordination of phenylcarboranes with a chromium tricarbonyl group inhibits the process of dehydrogenation of the carborane nucleus under electron impact.

     

Keywords

Mass Spectrometry Chromium Dehydrogenation Electron Impact Tricarbonyl 

Literature cited

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    M. R. Litzow and T. R. Spalding, Mass Spectrometry of Inorganic and Organometallic Compounds, Elsevier, Amsterdam (1973), p. 115.Google Scholar

Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • N. I. Vasyukova
    • 1
  • Yu. S. Nekrasov
    • 1
  • Yu. N. Sukharev
    • 1
  • G. K. -I. Magomedov
    • 1
  • A. S. Frenkel'
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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