Advertisement

Mass spectrometry of π complexes of transition metals. Communication 33. Carboranyl derivatives of benzenechromium tricarbonyl

  • N. I. Vasyukova
  • Yu. S. Nekrasov
  • Yu. N. Sukharev
  • G. K. -I. Magomedov
  • A. S. Frenkel'
Physical Chemistry

Conclusions

  1. 1.

    The degree of fragmentation of carboranyl derivatives of benzenechromium tricarbonyl with cleavage of metal-ligand bonds depends linearly on the number of vibrational degrees of freedom of the π ligand.

     
  2. 2.

    Coordination of phenylcarboranes with a chromium tricarbonyl group inhibits the process of dehydrogenation of the carborane nucleus under electron impact.

     

Keywords

Mass Spectrometry Chromium Dehydrogenation Electron Impact Tricarbonyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    N. I. Vasyukova, D. V. Zagorevskii, V. V. Kobak, A. I. Kovredov, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 2246 (1984).Google Scholar
  2. 2.
    Yu. S. Nekrasov and N. I. Vasyukova, Org. Mass Spectrom.,14, 422 (1979).Google Scholar
  3. 3.
    J. R. Gilbert, W. P. Leach, and J. E. Miller, J. Organomet. Chem.,49, 219 (1973).Google Scholar
  4. 4.
    V. I. Baidin, T. V. Klimova, Yu. S. Nekrasov, G. K. Semin, and V. I. Stanko, Zh. Prikl. Spektrosk.,36, 160 (1982).Google Scholar
  5. 5.
    Yu. N. Sukharev and Yu. S. Nekrasov, Org. Mass Spectrom.,11, 1232 (1976).Google Scholar
  6. 6.
    M. R. Litzow and T. R. Spalding, Mass Spectrometry of Inorganic and Organometallic Compounds, Elsevier, Amsterdam (1973), p. 115.Google Scholar

Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • N. I. Vasyukova
    • 1
  • Yu. S. Nekrasov
    • 1
  • Yu. N. Sukharev
    • 1
  • G. K. -I. Magomedov
    • 1
  • A. S. Frenkel'
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

Personalised recommendations