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19F and199Hg NMR spectra of certain fluorine-containing arylmercury derivatives of acetylenes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

19F and199Hg NMR have been used to investigate the comparative influence of electronic effects of the substituents on the shielding of19F and199Hg nuclei in ArHgC-CC6H4F-4 and 4-FC6H4HgC=CR. It has been found that the shielding of the fluorine decreases and the shielding of the mercury increases with increasing electron-acceptor properties of the Ar or R, or when the change is made from toluene to pyridine. The19F and199Hg chemical shifts correlate well with the σ and σ0 Hammett constants.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. S. Peregudov, V. F. Ivanov, É. I. Fedin & D. N. Kravtsov

Authors
  1. A. S. Peregudov
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  2. V. F. Ivanov
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  3. É. I. Fedin
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  4. D. N. Kravtsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1524–1529, July, 1985.

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Peregudov, A.S., Ivanov, V.F., Fedin, É.I. et al. 19F and199Hg NMR spectra of certain fluorine-containing arylmercury derivatives of acetylenes. Russ Chem Bull 34, 1394–1399 (1985). https://doi.org/10.1007/BF00950137

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  • DOI: https://doi.org/10.1007/BF00950137

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