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Nature of13C NMR paramagnetic shifts induced by Cr(acac)3 in molecules of organic solvents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    For a broad circle of organic compounds, interaction with Cr(acac) leads to the appearance of appreciable spin density on the carbon atoms.

  2. 2.

    The outer-sphere interactions responsible for transfer of spin density have a donoracceptor character.

  3. 3.

    An analogy exists between the relationships governing delocalization of spin density in molecular complexes of organic radicals and in outer-sphere adducts of metal complexes.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. N. Kitaigorodskii

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  1. A. N. Kitaigorodskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1518–1524, July, 1985.

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Kitaigorodskii, A.N. Nature of13C NMR paramagnetic shifts induced by Cr(acac)3 in molecules of organic solvents. Russ Chem Bull 34, 1388–1393 (1985). https://doi.org/10.1007/BF00950136

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  • DOI: https://doi.org/10.1007/BF00950136

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