Skip to main content
SpringerLink
Log in

Nature of the donor-acceptor reaction of maleic anhydride with the vinyl ether of benzyl alcohol

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The nature of the donor-acceptor complex of maleic anhydride with the vinyl ether of benzyl alcohol was studied by NMR, UV spectroscopic, dielectrometric titration, and quantum-chemical methods; the equilibrium constant was-determined.

  2. 2.

    The formation of a π complex with weak charge transfer from the HOMO of the phenyl group and the HOMO of the vinyloxy group to the lowest unoccupied orbitals of the anhydride was demonstrated for the donor-acceptor reaction of maleic anhydride and the vinyl ether of benzyl alcohol.

  3. 3.

    In complexing of the vinyl ether of benzyl alcohol with maleic anhydride, the reactivity of the double bonds of the monomers is decreased in the copolymerization reaction, since the structure of the complex causes steric shielding of the Cβ atom in the double bond in the ether by the anhydride groups.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. I. Smirnov, T. L. Petrova, A. V. Kalabina, V. B. Golubev, and V. P. Zubov, Vysokomol. Soedin.,B24, 303 (1982).

    Google Scholar 

  2. A. I. Smirnov, G. I. Deryabina, T. L. Petrova, G. S. Georgiev, V. B. Golubev, and V. P. Zubov, Vysokomol. Soedin.,A23, 407 (1981).

    Google Scholar 

  3. A. I. Smirnov, G. I. Deryabina, A. V. Kalabina, G. V. Ratovskii, and V. L. Beloborodov, Vysokomol. Soedin.,B17, 829 (1975).

    Google Scholar 

  4. T. I. Rozova, Dissertation, Irkutsk (1983).

  5. A. I. Smirnov, G. I. Deryabina, G. V. Ratovskii, G. A. Kalabin, D. F. Kushnarev, T. L. Petrova, and Yu. L. Frolov, Izv. Akad. Nauk SSSR, Ser. Khim., 74 (1977).

  6. G. Kuehlenz and H. H. Jaffe, J. Chem. Phys.,58, 2238 (1973).

    Google Scholar 

  7. L. V. Vilkov, V. S. Mastrukov, and N. I. Sadova, Determination of the Geometric Structure of Free Molecules [in Russian], Khimiya, Leningrad (1978), p. 224.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Irkutsk

    T. L. Petrova, A. I. Smirnov, G. V. Ratovskii, D. D. Chuvashev, V. B. Modonov, V. B. Mantsivoda & V. P. Zubov

  2. A. A. Zhdanov Irkutsk State University, USSR

    T. L. Petrova, A. I. Smirnov, G. V. Ratovskii, D. D. Chuvashev, V. B. Modonov, V. B. Mantsivoda & V. P. Zubov

Authors
  1. T. L. Petrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. V. Ratovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. D. Chuvashev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. B. Modonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. B. Mantsivoda
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. P. Zubov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1499–1504, July, 1985.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Petrova, T.L., Smirnov, A.I., Ratovskii, G.V. et al. Nature of the donor-acceptor reaction of maleic anhydride with the vinyl ether of benzyl alcohol. Russ Chem Bull 34, 1371–1376 (1985). https://doi.org/10.1007/BF00950132

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00950132

Keywords

Search

Navigation