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Electronic absorption spectra of charge-transfer complexes based on ferrocene and polyhalohydrocarbons

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Polyhalohydrocarbons containing CHHal2 and CHal3 groups (Hal=Cl, Br) form with ferrocene charge-transfer complexes (CTC).

  2. 2.

    Polyhalomethanes and polyhalo-2-pentenes show the highest activity in the reaction of complex formation with ferrocene. The compounds with the CBr3 group in CTC have the highest extinction.

  3. 3.

    An elongation of the alkyl chain in the molecule of polyhalogen derivatives and the presence of an additional halogen atom in the γ position with respect to the CHal3 group do not exert any significant influence on their CTC spectra with ferrocene.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Akademy of Sciences of the USSR, Moscow

    L. F. Germanova, L. V. Balabanova, T. T. Vasil'eva, M. -G. A. Shvekhgeimer, N. S. Kochetkova & B. V. Nelyubin

Authors
  1. L. F. Germanova
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  2. L. V. Balabanova
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  3. T. T. Vasil'eva
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  4. M. -G. A. Shvekhgeimer
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  5. N. S. Kochetkova
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  6. B. V. Nelyubin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1490–1493, July, 1985.

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Germanova, L.F., Balabanova, L.V., Vasil'eva, T.T. et al. Electronic absorption spectra of charge-transfer complexes based on ferrocene and polyhalohydrocarbons. Russ Chem Bull 34, 1363–1365 (1985). https://doi.org/10.1007/BF00950130

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  • DOI: https://doi.org/10.1007/BF00950130

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