Conclusions
The reaction of ethyl diphenylthiophosphinite with Ph2PCl leads to the formation of tetraphenyldiphosphine, ethyldiphenylphosphine Sulfide, and diphenylchlorophosphine sulfide. Phenyl diphenylthiophosphinite under drastic conditions undergoes isomerization to triphenylphosphine sulfide.
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Literature cited
K. M. Abraham and J. R. Van Wazer, Phosphorus,6, 23 (1975).
V. A. Al'fonsov, G. U. Zamaletdinova, É. S. Batyeva, and A. N. Pudovik, Zh. Obshch. Khim.,51, 11 (1981).
V. A. Al'fonsov, G. U. Zamaletdinova, É. I. Gol'dfarb, A. V. Il'yasov, É. S. Batyeva, and A. N. Pudovik, Zh. Obshch. Khim.,50, 680 (1980).
K. Moedritzer, G. M. Burch, J. R. Van Wazer, and H. K. Hofmeister, Inorg. Chem.,1963, 1152.
M. M. Grutfield, C. H. Dungan, J. H. Letber, V. Mark, and J. R. Van Wazer, Topics in Phosphorus Chemistry, Vol. 5, Interscience, New York-London (1967), p. 298.
D. H. Brown, R. I. Cross, and R. Keat, J. Chem. Soc. Chem. Commun.,1977, 708.
W. Kuchen and H. Buchwald, Angew. Chem.,91, 871 (1958).
A. E. Arbuzov, Selected Works on the Chemistry of Organophosphorus Compounds [in Russian], Nauka, Moscow (1976), p. 160.
W. Strecker and C. Grossman, Chem. Ber.,49, 63 (1916).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 951–952, April, 1982.
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Al'fonsov, V.A., Pudovik, D.A., Batyeva, É.S. et al. Reaction of diphenylthiophosphinous esters with diphenylchlorophosphine. Russ Chem Bull 31, 843–844 (1982). https://doi.org/10.1007/BF00950039
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DOI: https://doi.org/10.1007/BF00950039