Conclusions
-
1.
A noticeable effect of longitudinal mixing on the shape of the exit curves of the elution process can be expected when the values of the parameter Ω ≳10−3.
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2.
At very high values of Ω the longitudinal mixing can shift the position of the zone maximum.
Literature cited
G. É. El'kin, Yu. Ya. Lebedev, and G. V. Samsonov, Vysokomol. Soedin.,A17, 1870 (1975).
L. K. Shataeva, N. N. Kuznetsova, and G. É. El'kin, Carboxyl Cationites in Biology [in Russian], Nauka, Leningrad (1979).
M. M. Senyavin, R. N. Rubinshtein, E. V. Venetsianov, N. K. Galkina, I. V. Komarova, and V. A. Nikashina, Principles of Calculation and Optimization of Ion-Exchange Processes [in Russian], Nauka, Moscow (1972).
V. A. Ditkin and A. P. Prudnikov, Integral Transformations and Operational Calculation [in Russian], Nauka, Moscow (1974).
G. É. El'kin, A. T. Melenevskii, and G. V. Samsonov, Vysokomol. Soedin.,B16, 871 (1974).
E. Kŭcera, J. Chromatogr.,19, 237 (1965).
L. Z. Vilenchik, V. I. Kolegov, and B. G. Belen'kii, Zh. Fiz. Khim.,46, 1109 (1972).
P. P. Zolotarev and L. V. Radushkevich, Izv. Akad. Nauk SSSR, Ser. Khim.,1968, 1906.
G. É. El'kin, A. T. Melenevskii, and G. V. Samsonov, in monograph: Molecular Liquid Chromatography, Abstracts of Papers [in Russian], Nauka, Chernogolovka (1979), p. 51.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 946–949, April, 1982.
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El'kin, G.É., Melenevskii, A.T., Chizhova, E.B. et al. Elution chromatography during intradiffusion kinetics and longitudinal mixing. Russ Chem Bull 31, 838–841 (1982). https://doi.org/10.1007/BF00950037
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DOI: https://doi.org/10.1007/BF00950037