Conclusions
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1.
A study was made of the reactivity of some alkynol and analogous alkyl esters of phosphorus thioacids in alkaline medium.
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2.
It was established that the insertion of the acetylene bond β to the phosphorylmercapto group leads to an increase in the alkaline hydrolysis rate.
Literature cited
L. A. Vikhreva, T. A. Pudova, I. B. Nemirovskaya, D. I. Lobanov, N. N. Godovikov, M. I. Kabachnik, S. A. Roslavtseva, and T. A. Spirina, USSR Patent 630,860 (1978); Byull. Izobr., No. 31 (1979).
L. A. Vikhreva, T. A. Pudova, I. B. Nemirovskaya, N. N. Godovikov, M. I. Kabachnik, N. A. Guseva, T. N. Kaluzhina, A. S. Sedykh, and S. A. Roslavtseva, USSR Patent 677, 398 (1979); Byull. Izobr., No. 13 (1981).
N. N. Godovikov, L. A. Vikhreva, T. A. Pudova, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim.,1980, 2588.
Ya. L. Yarv and A. A. Aaviksaar, Reakts. Sposobn. Org. Soedin.,8, 965–980 (1971).
R. I. Volkova, N. N. Godovikov, M. I. Kabachnik, L. G. Magazanik, T. A. Mastryukova, M. Ya. Mikhel'son, E. K. Rozhkova, N. K. Fruentov, and V. A. Yakovlev, Vopr. Med. Khim.,7, 250 (1961).
M. I. Kabachnik, T. A. Mastryukova, and N. I. Kurochkin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1956, 193.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 944–945, April, 1982.
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Evreinov, V.I., Petrova, L.N., Vikhreva, L.A. et al. Alkaline hydrolysis of ω-substituted S-butyne esters of phosphorus thioacids. Russ Chem Bull 31, 836–837 (1982). https://doi.org/10.1007/BF00950036
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DOI: https://doi.org/10.1007/BF00950036