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Catalysts for polymerization of cycloolefins based on tungsten hexachloride with permethylpolysilanes and permethylpolygermanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Catalysts based on WCl6, activated by either permethylpolysilanes or permethylpolygermanes, are active in the polymerization of cycloolefins, with ring opening by the metathesis scheme.

  2. 2.

    The use of permethylpolygermanes as cocatalysts leads to polymers that contain at least 90% of cis links.

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Literature cited

  1. N. S. Nametkin, V. M. Vdovin, É, D. Babich, V. N. Karel'skii, and B. V. Kacharmin, Dokl. Akad. Nauk SSSR,213, 356 (1973).

    Google Scholar 

  2. N. B. Bespalova, É. D. Babich, V. M. Vdovin, and N. S. Nametkin, Dokl. Akad. Nauk SSSR,225, 1071 (1975).

    Google Scholar 

  3. L. I. Red'kina, I. A. Oreshkin, K. L. Makovetskii, É. D. Babich, and V. M. Vdovin, Izv. Akad. Nauk SSSR, Ser. Khim.,1980, 1214.

  4. N. B. Bespalova and É. D. Babich, in: Abstracts of Papers Delivered at Fifth All-Union Conference on the Chemistry and Application of Organosilicon Compounds, Tbilisi, 1980, Vol. 1 [in Russian], GNIIKhTÉOS, Moscow (1980), p. 65.

    Google Scholar 

  5. É. D. Babich, N. B. Bespalova, V. M. Vdovin, T. K. Gar, and V. F. Mironov, Izv. Akad. Nauk SSSR, Ser. Khim., 1977, 960.

  6. V. F. Traven', V. N. Karel'skii, V. F. Donyagina, É. D. Babich, V. M. Vdovin, and B. I. Stepanov, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1681.

  7. V. F. Traven', V. N. Karel'skii, V. F. Donyagina, É. D. Babich, B. I. Stepanov, V. M. Vdovin, and N. S. Nametkin, Dokl. Akad. Nauk SSSR,224, 837 (1975).

    Google Scholar 

  8. O. M. Nefedov and M. N. Manakov, USSR Patent 143, 803 (1961); Byull. Izobr., No. 1 (1962).

  9. O. M. Nefedov, M. N. Manakov, and A. D. Petrov, Dokl. Akad. Nauk SSSR,147, 1376 (1962).

    Google Scholar 

  10. O. M. Nefedov, S. P. Kolesnikov, G. Garzo, M. Blazho, I. Tamash, and A. K. Mal'tsev, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 1395.

  11. V. F. Traven', V. F. Donyagina, I. G. Makarov, S. P. Kolesnikov, V. M. Kazakova, and B. I. Stepanov, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 1042.

  12. V. I. Shiryaev, Dissertation [in Russian], Moscow (1968), p. 142.

  13. A. P. Korobko, V. S. Turov, and V. M. Cherednichenko, Vysokomol. Soedin.,17, 195 (1975).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. P. Kolesnikov, T. L. Mitenina, A. Ya. Shteinshneider & O. M. Nefedov

Authors
  1. S. P. Kolesnikov
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  2. T. L. Mitenina
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  3. A. Ya. Shteinshneider
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  4. O. M. Nefedov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 942–943, April, 1982.

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Kolesnikov, S.P., Mitenina, T.L., Shteinshneider, A.Y. et al. Catalysts for polymerization of cycloolefins based on tungsten hexachloride with permethylpolysilanes and permethylpolygermanes. Russ Chem Bull 31, 834–835 (1982). https://doi.org/10.1007/BF00950035

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  • DOI: https://doi.org/10.1007/BF00950035

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