Skip to main content
SpringerLink
Log in

[2π+2π] Catalytic homo- and codimerization of substituted norbornadienes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dimerization and codimerization of 2- and 7-substituted norbornadienes in the presence of low-valent iron complexes gives new mono- and 5(6), 11-disubstituted exo-trans-exopentacyclo [8.2.1.14,702,90.3,8]tetradeca-5,11-dienes in high yields.

  2. 2.

    According to photoelectronic spectral data, introduction of substituents into the 2- and 7-positions of norbornadiene does not result in any significant changes in the interaction energies of the double bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. G. N. Schrauzer, Adv. Catal.,18, 373 (1968).

    Google Scholar 

  2. T. J. Katz, J. C. Carnahan, and R. Boecke, J. Org. Chem.,32, 1301 (1967).

    Google Scholar 

  3. P. W. Jolly, F. G. A. Stone, and K. Mackenzie, J. Chem. Soc., 6416 (1965).

  4. M. Ennis, R. M. Foley, and A. R. Manning, J. Organomet. Chem.,166, cl8 (1979).

    Google Scholar 

  5. U. M. Dzhemilev, R. I. Khusnutdinov, Z. S. Muslimov, L. V. Spirikhin, G. A. Tolstikov, and O. M. Nefedov, Izv. Akad. Nauk SSSR, Ser. Khim., 2299 (1981).

  6. Ger. Offen 2 350 689; Chem. Abstr.,81, P25013s (1974).

  7. D. R. Arnold, D. J. Trecker, and E. B. Whipple, J. Am. Chem. Soc.,87, 2596 (1965).

    Google Scholar 

  8. P. Bishop, P. Hashmall, E. Heilbronner, and V. Hornung, Helv. Chim. Acta,52, 1745 (1969).

    Google Scholar 

  9. A. S. Onishchenko, The Diene Synthesis [in Russian], Izd. AN SSSR, Moscow (1963), pp. 290–292.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    S. R. Rafikov, U. M. Dzhemilev, R. I. Khusnutdinov, V. A. Dokichev, G. A. Tolstikov, A. Sh. Sultanov, B. G. Zykov & O. M. Nefedov

  2. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. R. Rafikov, U. M. Dzhemilev, R. I. Khusnutdinov, V. A. Dokichev, G. A. Tolstikov, A. Sh. Sultanov, B. G. Zykov & O. M. Nefedov

Authors
  1. S. R. Rafikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. U. M. Dzhemilev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. I. Khusnutdinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Dokichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. A. Tolstikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Sh. Sultanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. B. G. Zykov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. O. M. Nefedov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimlcheskaya, No. 4, pp. 902–907, April, 1982.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rafikov, S.R., Dzhemilev, U.M., Khusnutdinov, R.I. et al. [2π+2π] Catalytic homo- and codimerization of substituted norbornadienes. Russ Chem Bull 31, 795–799 (1982). https://doi.org/10.1007/BF00950022

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00950022

Keywords

Search

Navigation