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Arylolefins in modified prins reaction

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Acid-catalyzed cocondensation of formaldehyde and alkanals RCHO with styrene leads to 2-R-4-phenyl-1,3-dioxanes with equatorial orientation of substituent R in the 2-position, and with α-methylstyrene to a mixture of 4-methyl-2-R-4-phenyl-1,3-dioxanes with axial and equatorial orientation of substituent R.

The yield of the cocondensation products in this reaction reaches 60%.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    M. G. Safarov, N. G. Nigmatullin, U. G. Ibatullin & S. R. Rafikov

  2. Bashkir State University, Ufa

    M. G. Safarov, N. G. Nigmatullin, U. G. Ibatullin & S. R. Rafikov

Authors
  1. M. G. Safarov
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  2. N. G. Nigmatullin
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  3. U. G. Ibatullin
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  4. S. R. Rafikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 899–902, April, 1982.

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Safarov, M.G., Nigmatullin, N.G., Ibatullin, U.G. et al. Arylolefins in modified prins reaction. Russ Chem Bull 31, 792–794 (1982). https://doi.org/10.1007/BF00950021

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  • DOI: https://doi.org/10.1007/BF00950021

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