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A study of the kinetics of radiational graft polymerization of acrylic monomers on a butadiene-styrene thermoelastomer

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of radiochemical grafting of acrylonitrile and acrylic acid to a butadiene-styrene thermoelastomer have been studied by irradiating a material impregnated with the monomer; it has been shown that kinetic chain rupture in such systems is a monomolecular process.

  2. 2.

    The rate constant for propagation of the graft polyacrylonitrile chain and the activation energy for grafting have been calculated, the values obtained being close to those for homogeneous acrylonitrile polymerization.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    V. F. Timofeeva, G. G. Ryabchikova, A. K. Pikaev & V. I. Spitsyn

Authors
  1. V. F. Timofeeva
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  2. G. G. Ryabchikova
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  3. A. K. Pikaev
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  4. V. I. Spitsyn
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 881–884, April, 1982.

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Timofeeva, V.F., Ryabchikova, G.G., Pikaev, A.K. et al. A study of the kinetics of radiational graft polymerization of acrylic monomers on a butadiene-styrene thermoelastomer. Russ Chem Bull 31, 776–779 (1982). https://doi.org/10.1007/BF00950017

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  • DOI: https://doi.org/10.1007/BF00950017

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