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Crystal structures of cerium molybdenum and uranium molybdenum heteropoly acids

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Crystal structures of the cerium molybdenum and uranium molybdenum heteropoly acids have been determined for the first time.

  2. 2.

    A short distance between oxygen atoms of two neighboring polyanions has been found, which allows the suggestion of the presence of a hydrogen bond between them.

  3. 3.

    Distribution of the water molecules in the crystals of the acids is statistical.

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Literature cited

  1. D. D. Dexter and J. V. Silverton, J. Am. Chem. Soc.,90, 3589 (1968).

    Google Scholar 

  2. I. V. Tat'yanina, T. S. Chernaya, E. A. Torchenkova, V. I. Simonov, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,247, 1162 (1979).

    Google Scholar 

  3. I. V. Tat'yanina, V. E. Zavodnik, E. B. Fomicheva, V. K. Bel'skii, V. I. Molchanov, and E. A. Torchenkova, Abstracts of Proceedings of the Fourth All-Union Conference on Chemistry and Technology of Molybdenum and Tungsten [in Russian], Vol. 2 (1980), p. 126.

    Google Scholar 

  4. V. N. Molchanov, I. V. Tatjanina (Tat'yanina), E. A. Torchenkova, and L. P. Kazansky (Kazanskii), J. Chem. Soc., Chem. Commun., 93 (1981).

  5. P. Baidala, E. A. Torchenkova, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,196, 1344 (1971).

    Google Scholar 

  6. P. Baidala, V. S. Smurova, E. A. Torchenkova, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,197, 339 (1971).

    Google Scholar 

  7. A. B. Tovbis and B. M. Shchedrin, Kristallografiya,15, 1127 (1970).

    Google Scholar 

  8. Program Complex of the Enraf-Nonius SDP Firm.

  9. L. P. Kazanskii, E. A. Torchenkova, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,209, 141 (1973).

    Google Scholar 

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    I. V. Tat'yanina, V. N. Molchanov, V. M. Popov, E. A. Torchenkova & V. I. Spitsyn

Authors
  1. I. V. Tat'yanina
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  2. V. N. Molchanov
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  3. V. M. Popov
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  4. E. A. Torchenkova
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  5. V. I. Spitsyn
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 803–807, April, 1982.

The authors thank V. E. Zavodnik and V. K. Bel'skii for carrying out the diffractometric experiment.

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Tat'yanina, I.V., Molchanov, V.N., Popov, V.M. et al. Crystal structures of cerium molybdenum and uranium molybdenum heteropoly acids. Russ Chem Bull 31, 707–710 (1982). https://doi.org/10.1007/BF00950003

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  • DOI: https://doi.org/10.1007/BF00950003

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