199Hg chemical shifts of phenylmercury thiophenolates

  • Yu. K. Grishin
  • Yu. A. Strelenko
  • Yu. A. Ustynyuk
  • A. S. Peregudov
  • L. S. Golovchenko
  • E. M. Rokhlina
  • D. N. Kravtsov
Physical Chemistry
  • 18 Downloads

Conclusions

  1. 1.

    The introduction of substituents into the meta and para positions of the thiophenol ring in phenylmercury derivatives of thiophenols results in an increase in mercury shielding.

     
  2. 2.

    The presence of intramolecular coordination bonding between the metal atom and ortho substituents is demonstrated.

     
  3. 3.

    Coordinating and polar solvents increase mercury shielding.

     

Keywords

Mercury Chemical Shift Metal Atom Polar Solvent Para Position 

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • Yu. K. Grishin
    • 1
    • 2
  • Yu. A. Strelenko
    • 1
    • 2
  • Yu. A. Ustynyuk
    • 1
    • 2
  • A. S. Peregudov
    • 1
    • 2
  • L. S. Golovchenko
    • 1
    • 2
  • E. M. Rokhlina
    • 1
    • 2
  • D. N. Kravtsov
    • 1
    • 2
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow
  2. 2.M. V. Lomonosov Moscow State UniversityUSSR

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