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Termal stability of diiron hexacarbonyl complexes obtained from aromatic azines

  • V. V. Trusov
  • N. A. Nechitailo
  • V. D. Tyurin
  • M. A. Dzyubina
  • N. S. Nametkin
Brief Communications
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Conclusions

  1. 1.

    The thermogravimetric method was used to study the thermal stability of some diiron hexacarbonyl complexes that were obtained from aromatic azines. The incipient decomposition temperatures of the complexes, which contain two three-electron nitrogen-containing bridges, are independent of the structure of the ligand.

     
  2. 2.

    The complexes decompose in three steps, with the successive removal of carbonyl groups and the corresponding nitrogen-containing ligand.

     

Keywords

Thermal Stability Carbonyl Carbonyl Group Decomposition Temperature Azine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • V. V. Trusov
    • 1
  • N. A. Nechitailo
    • 1
  • V. D. Tyurin
    • 1
  • M. A. Dzyubina
    • 1
  • N. S. Nametkin
    • 1
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisAcademy of Sciences of the USSRMoscow

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