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Initiated joint oxidation of n-paraffins and polyhydric alcohols and esters

  • T. G. Degtyareva
  • E. T. Denisov
  • V. S. Martem'yanov
  • I. A. Kaftan
  • L. R. Enikeeva
Physical Chemistry
  • 30 Downloads

Conclusions

  1. 1.

    Rates of initiated joint oxidation in 52 binary R1H-R2H systems: n-paraffin-alcohol, n-paraffin-ester, ester- alcohol, alcohol-ether have been obtained from measurements of O2 uptake at 403°K. The reactivity of R2H relative to R1OO· has been estimated in those cases in which the rate of oxidation was increased by addition of the second component.

     
  2. 2.

    A multidipole effect appears in the reactions of polyfunctional alcohols and esters with peroxide radicals. The contribution of this effect to the Gibbs activation energy varies from 2.4 to 6.1 kJ/mole, depending on the structure. The activity of the peroxide radical also depends on the number and type of the functional groups in the molecule.

     

Keywords

Oxidation Alcohol Ester Peroxide Activation Energy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 1746 (1978).Google Scholar
  2. 2.
    E. T. Denisov, N. I. Mitskevich, and V. Agabekov, The Mechanism of Liquid-Phase Oxidation of Oxygen-Containing Compounds [in Russian], Nauka i Tekhnika, Minsk (1975).Google Scholar
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    G. G. Agliullina, V. S. Martem'yanov, E. T. Denisov, and T. I. Eliseeva, Izv. Akad. Nauk SSSR, Ser. Khim., 50 (1977).Google Scholar
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    T. G. Degtyareva, E. T. Denisov, V. S. Martem'yanov, and L. Ya. Badretdinova, Izv. Akad. Nauk SSSR, Ser. Khim., 1219 (1979).Google Scholar
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    E. T. Denisov, Rate Constants for Homolytic Liquid Reactions [in Russian], Nauka, Moscow (1971).Google Scholar
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    N. M. Émanuél', E. T. Denisov, and Z. K. Maizus, Chain Reactions in Liquid-Phase Hydrocarbon Oxidations [in Russian], Nauka, Moscow (1965).Google Scholar

Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • T. G. Degtyareva
    • 1
    • 2
  • E. T. Denisov
    • 1
    • 2
  • V. S. Martem'yanov
    • 1
    • 2
  • I. A. Kaftan
    • 1
    • 2
  • L. R. Enikeeva
    • 1
    • 2
  1. 1.Branch of the Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka
  2. 2.Bashkir State UniversityUfa

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