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Sulfenylation of fluorinated CH acids

  • Yu. V. Zeifman
  • L. T. Lantseva
Organic Chemistry

Conclusions

  1. 1.

    Fluorinated CH acids smoothly react with sulfenyl chlorides in the presence of Et3N to give either alkyl or aryl polyfluoroalkyl sulfides and polyfluoroalkyl sulfenamides.

     
  2. 2.

    In a number of reactions the bis(trifluoromethyl)alkyl(aryl)thiomethyl group is effectively leaving as the anion.

     
  3. 3.

    2-Ethylthiopentafluoropropylene was synthesized and its transformations during catalysis by fluorine anion were studied.

     

Keywords

Chloride Sulfide Catalysis Fluorine Trifluoromethyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • Yu. V. Zeifman
    • 1
  • L. T. Lantseva
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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