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Sulfenylation of fluorinated CH acids

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Fluorinated CH acids smoothly react with sulfenyl chlorides in the presence of Et3N to give either alkyl or aryl polyfluoroalkyl sulfides and polyfluoroalkyl sulfenamides.

  2. 2.

    In a number of reactions the bis(trifluoromethyl)alkyl(aryl)thiomethyl group is effectively leaving as the anion.

  3. 3.

    2-Ethylthiopentafluoropropylene was synthesized and its transformations during catalysis by fluorine anion were studied.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    Yu. V. Zeifman & L. T. Lantseva

Authors
  1. Yu. V. Zeifman
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  2. L. T. Lantseva
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1102–1106, May, 1980.

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Zeifman, Y.V., Lantseva, L.T. Sulfenylation of fluorinated CH acids. Russ Chem Bull 29, 809–813 (1980). https://doi.org/10.1007/BF00949691

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  • DOI: https://doi.org/10.1007/BF00949691

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