Sulfenylation of fluorinated CH acids
Fluorinated CH acids smoothly react with sulfenyl chlorides in the presence of Et3N to give either alkyl or aryl polyfluoroalkyl sulfides and polyfluoroalkyl sulfenamides.
In a number of reactions the bis(trifluoromethyl)alkyl(aryl)thiomethyl group is effectively leaving as the anion.
2-Ethylthiopentafluoropropylene was synthesized and its transformations during catalysis by fluorine anion were studied.
KeywordsChloride Sulfide Catalysis Fluorine Trifluoromethyl
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