Conclusions
-
1.
The nature of the coefficients A and B in the equations describing the dependence of the free energy of solution on the retention index has been analyzed.
-
2.
The changes in the free energy of solution of aliphatic sulfides and disulfides upon replacement of an alkyl group by isoalkyl and unsaturated groups, as well as upon displacement of the sulfur atom in metameric thiatridecanes, have been evaluated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
R. V. Golovnya and Yu. N. Arsen'ev (Arsenyev), Chromatographia,4, 250 (1971).
R. V. Golovnya, V. G. Garbuzov, and T. A. Misharina, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 2266.
R. V. Golovnya, T. A. Misharina, and V. G. Garbuzov, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, 387;1978, 2539;1979, 2039.
A. W. Littlewood, C. S. C. Phillips, and D. T. Price, J. Chem. Soc.,1955, 1480.
Yu. N. Arsen'ev, Dissertation, Moscow (1972).
D. Ambrose, A. I. M. Keulemans, and J. H. Purnell, Anal. Chem.,30, 1583 (1958).
R. V. Golovnya, G. A. Mironov, and I. L. Zhuravleva, Dokl. Akad. Nauk SSSR,163, 369 (1965).
S. S. Yufit, B. A. Rudenko, Zh. A. Krasnaya, and V. F. Kucherov, Dokl. Akad. Nauk SSSR,188, 156 (1969).
R. V. Golovnya and T. A. Misharina, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 1794.
B. N. Anvaer, A. A. Zhukhovitskii, and N. M. Turkel'taub, Gas Chromatography [in Russian], GOSINTI (1962), p. 44.
R. V. Golovnya and T. E. Kusmenko, Chromatographia,9, 545 (1977).
W. O. McReynolds, Gas-Chromatographie Retention Data, Preston Technical Abstract Co., Evanston, Illinois (1966).
T. H. Risby, P. C. Jurs, and B. L. Reinhold, J. Chromatogr.,99, 171 (1974).
B. L. Reinhold and T. H. Risby, J. Chromatogr. Sci.,13, 372 (1975).
C. E. Figgins, T. H. Risby, and P. S. Jurs, J. Chromatogr. Sci.,14, 453 (1976).
C. E. Figgins, B. L. Reinhold, and P. S. Jurs, J. Chromatogr. Sci.,15, 208 (1977).
J. Novàk, J. Ruzickova, S. Wicàr, and J. Janàk, Anal. Chem.,45, 1365 (1973).
J. Novàk, J. Chromatogr.,78, 269 (1973).
J. Novàk and J. Ruzickova, J. Chromatogr.,91, 79 (1974).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2764–2770, December, 1980.
Rights and permissions
About this article
Cite this article
Golovnya, R.V., Misharina, T.A. Gas-chromatographic determination of energy contributions of isoaliphatic and unsaturated groups in sulfides and disulfides and of sulfur atoms in metameric thiatridecanes from retention indices. Russ Chem Bull 29, 1937–1942 (1980). https://doi.org/10.1007/BF00949661
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00949661