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Volt-amperometric study of the oxidation of anions of gem-dinitroalkanes

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The nature of the anodic waves on the polarization curves of anions of gem-dinitro-alkanes has been established. It has been shown that the oxidation of these anions is a multistage process, and the electrode reaction at the potentials of the first waves includes the oxidation of the intermediately formed particles NO −2 and NO, while the second wave corresponds to the oxidation of the NO −3 ion.

  2. 2.

    The electrooxidation of anions of gem-dinitroalkanes leads to the formation of the corresponding un-ionized dinitro compounds in high yield part of the initial anions being consumed in side reactions of nonelectrochemical nature.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Petrosyan, M. E. Niyazymbetov, A. G. Bazanov, I. V. Tselinskii & A. A. Fainzil'berg

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  1. V. A. Petrosyan
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  2. M. E. Niyazymbetov
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  3. A. G. Bazanov
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  4. I. V. Tselinskii
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  5. A. A. Fainzil'berg
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2726–2730, December, 1980.

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Petrosyan, V.A., Niyazymbetov, M.E., Bazanov, A.G. et al. Volt-amperometric study of the oxidation of anions of gem-dinitroalkanes. Russ Chem Bull 29, 1901–1905 (1980). https://doi.org/10.1007/BF00949653

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  • DOI: https://doi.org/10.1007/BF00949653

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