Skip to main content
SpringerLink
Log in

β-CH regeneration of antioxidants in N,N-diethylacetamide

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The liquid-phase oxidation of N,N-diethylamide (DEA) by molecular oxygen proceeds by a radical-chain mechanism with quadratic chain termination. The rate constants for chain propagation and termination have been measured.

  2. 2.

    It has been discovered that multiple chain termination by a single antioxidant molecule occurs in DEA during oxidation. This is explained by the redox properties of the α-peroxy radicals of the amide. Aβ-CH bond is necessary for these properties to be exhibited. The rate constants and stoichiometric coefficients for inhibition by various types of antioxidant have been measured at 75°C.

  3. 3.

    The rate constants for initiation by azobisisobutyronitrile (75°C) and azobiscyclo-hexanecarbonitrile (90°C) have been measured in DEA.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. L. Aleksandrov, Neftekhimiya,18, 553 (1978).

    Google Scholar 

  2. T. I. Sapacheva, G. G. Agliullina, A. L. Aleksandrov, and E. T. Denisov, Neftekhimiya,14, 623 (1974).

    Google Scholar 

  3. T. I. Sapacheva, G. G. Agliullina, and A. L. Aleksandrov, Neftekhimiya,14, 450 (1974).

    Google Scholar 

  4. U. Ya. Samatov, A. L. Aleksandrov, and I. R. Akhunov, Izv. Akad. Nauk SSSR, Ser. Khim., 2254 (1978).

  5. B. F. Sagar, J. Chem. Soc. B, 428 (1967).

  6. G. A. Kovtun, A. V. Kazantsev, and A. L. Aleksandrov, Izv. Akad. Nauk SSSR, Ser. Khim., 2635 (1974).

  7. G. Sh. Bakhturidze, A. L. Aleksandrov, and I. L. Édilashvili, Izv. Akad. Nauk SSSR, Ser. Khim., 515 (1971).

  8. A. L. Aleksandrov and L. D. Krisanova, Izv. Akad. Nauk SSSR, Ser. Khim., 2469 (1980).

  9. N. N. Pozdeeva, T. I. Sapacheva, and A. L. Aleksandrov, Izv. Akad. Nauk, Ser. Khim., 1738 (1976).

  10. E. M. Pliss, A. L. Aleksandrov, V. S. Mikhlin, and M. M. Mogilevich, Izv. Akad. Nauk SSSR, Ser. Khim., 2259 (1978).

  11. A. L. Buchachenko and A. M. Vasserman, Stable Radicals [in Russian], Khimiya (1973), pp. 375, 376.

  12. G. A. Kovtun, V. A. Golubev, and A. L. Aleksandrov, Izv. Akad. Nauk SSSR, Ser. Khim., 793, 2197 (1974).

    Google Scholar 

  13. N. M. Émanuél', E. T. Denisov, and Z. K. Maizus, Liquid-Phase Hydrocarbon Oxidation Chain Reactions [in Russian], Nauka (1965), pp. 219, 221.

  14. E. M. Pliss and A. L. Aleksandrov, Izv. Akad. Nauk SSSR, Ser. Khim., 214 (1978).

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Division, USSR

    A. L. Aleksandrov

Authors
  1. A. L. Aleksandrov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2720–2725, December, 1980.

The author wishes to thank M. F. Semenova for participating in the experimental part of this work.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aleksandrov, A.L. β-CH regeneration of antioxidants in N,N-diethylacetamide. Russ Chem Bull 29, 1896–1901 (1980). https://doi.org/10.1007/BF00949652

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00949652

Keywords

Search

Navigation