Oxidative dehydrogenation of cyclohexene to benzene by oxygen, catalyzed by a palladium cluster

  • A. S. Berenblyum
  • A. G. Knizhnik
  • S. L. Mund
  • I. I. Moiseev
Physical Chemistry

Conclusions

  1. 1.

    A reaction mechanism is proposed for the oxidative dehydrogenation of cyclohexene by oxygen to benzene, catalyzed with a (PPh)2Pd5 cluster, including reversible complexing of cyclohexene with (PPh)2Pd5, the rupture of the C-H bond of coordinated cyclohexene, and the reaction of the resulting complex and O3 with the generation of reaction products and reversible interaction of (PPh)2Pd5 with the benzene.

     
  2. 2.

    The equilibrium constants of (PPh)2Pd5 with cyclohexene and benzene, as well as the rate constant for the rupture of the C-H bond of the coordinated cyclohexene have been determined.

     

Keywords

Oxygen Benzene Palladium Cyclohexene Reaction Mechanism 

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Literature cited

  1. 1.
    A. S. Berenblyum, A. G. Knizhnik, S. L. Mund, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 2157 (1979).Google Scholar
  2. 2.
    I. V. Berezin and K. Martinek, Fundamentals of the Physical Chemistry of Enzymatic Catalysis [in Russian], Vysshaya Shkola, Moscow (1977), pp. 218, 251.Google Scholar
  3. 3.
    G. M. Schwab, Lieb. Ann. Chem., 607, 1 (1957).Google Scholar
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    G. Allegra, G. Tettamanti Casagrande, A. Immizzi, and L. Porri, J. Am. Chem. Soc.,92, 289 (1970).Google Scholar

Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • A. S. Berenblyum
    • 1
    • 2
  • A. G. Knizhnik
    • 1
    • 2
  • S. L. Mund
    • 1
    • 2
  • I. I. Moiseev
    • 1
    • 2
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of SciencesMoscow
  2. 2.Elektrogorsk Branch of the All-Union Scientific-Research Institute of Petroleum RefiningUSSR

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